Personal Errors

Many measurements require personal judgments. Examples include estimating the position of a pointer between two scale divisions, the color of a solution at the end point in a titration, or the level of a liquid with respect to a graduation in a pipet or buret. Judgments of this type are often subject to systematic, unidirectional errors. For example, one person may read a pointer consistently high, while another may be slightly slow in activating a timer. Yet, a third may be less sensitive to color changes, with an analyst who is insensitive to color changes tending to use excess reagent in a volumetric analysis. Analytical procedures should always be adjusted so that any known physical limitations of the analyst cause negligibly small errors. Automation of analytical procedures can eliminate many errors of this type.

A universal source of personal error is prejudice, or bias. Most of us, no matter how honest, have a natural, subconscious tendency to estimate scale readings in a direction that improves the precision in a set of results. Alternatively, we may have a preconceived notion of the true value for the measurement. We then subconsciously cause the results to fall close to this value. Number bias is another source of personal error that varies considerably from person to person. The most frequent number bias encountered in estimating the position of a needle on a scale involves a preference for the digits 0 and 5. Also common is a prejudice favoring small digits over large and even numbers over odd. Again, automated and computerized instruments can eliminate this form of bias.

مواضيع ذات صلة

الشكل الوضعي للسكريات الأحادية configuration of monosaccharides

نظام استخلاص الجزئيات البسيطة

اختيار الطور الجديد وعدد مرات الاستخلاص

ميكانيكية الاستخلاص

طبيعة الصنف المستخلص

الاستخلاص بالمذيب

امتصاص الشعاع الكهرومغناطيسي وطيف الامتصاص

الطرق الكيميائية الطيفية في التحليل.

طبيعة الكيمياء التحليلية

التحليل بالحقن الجرياني المتقطع Batch flow injection analysis

الحقن الجرياني متعدد التخفيف Multi-commutation in FIA

التحليل بالحقن المتعاقب Sequential Injection Analysis