SULFURIC ACID (H₂SO₄₎

Sulfuric acid is the most important and widely used inorganic chemical. The 1994 U.S. production of sulfuric acid was 89.2 billion pounds. (most used industrial chemical).  Sulfuric acid is produced by the contact process where sulfur is burned in an air stream to sulfur dioxide, which is catalytically converted to sulfur trioxide. The catalyst of choice is solid vanadium pentoxide (V₂O₅). The oxidation reaction is exothermic, and the yield is favored at lower temperatures:

The reaction occurs at about 450°C, increasing the rate at the expense of a higher conversion. To increase the yield of sulfur trioxide, more than one conversion stage (normally three stages) is used with cooling between the stages to offset the exothermic reaction heat. Absorption of SO₃ from the gas mixture exiting from the reactor favors the conversion of SO₂. The absorbers contain sulfuric acid of 98% concentration which dissolves sulfur trioxide. The unreacted sulfur dioxide and oxygen are recycled to the reactor. The absorption reaction is exothermic, and special coolers are used to cool the acid:

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